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Ammonia
 

The diffusive sampler for ammonia collects gaseous ammonia by absorption on phosphoric acid. The amount of ammonia is determined spectrophotometrically by the indophenol method.

The passive samplers are composed of a polypropylene housing with an opening of 20 mm diameter. To reduce wind disturbance a teflon membrane is attached, supported by a wire net.

To protect the sampler from weather influences, as well as minimising wind disturbance, a protective shelter has to be used.

Diagram

Time series of a comparison of a continuous NH3 analyser and diffusion tube of ammonia [1].

 

Specifications

Samplingrate

31.5 ml/min at 20oC

Working range

0.5 — 20 µg/m3

Sampling time

2— 4 weeks

Detection limit

0.3 µg/m3 fortnight exposures

External influences:
   wind speed
Influence of wind speed < 10% up to 4.5 m/sec
using protection shelters
   temperature
no influence between 5 to 40oC
   humidity
no influence between 20 to 80%

Storage

before use: 4 months
after exposure: 2 months

Cross sensitivity

Solid particulates of ammonia are not collected

Expanded uncertainty*

27.4 % at concentration levels of 2 µg/m3

*according to GUM;
subject to change without notice
revised 3.1.2010

 

 
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